The presence of metal nanoparticles in CNT array, as it was shown in [20–23], plays the important role in the energy absorption by the array. The importance of the present investigation is defined by the possible
applications of the obtained selleck compound results. The arrays of CNTs with the intercalated ferromagnetic nanoparticles, so called magnetically functionalized CNTs (MFCNTs) [31, 32], may be considered as an ideal medium for different magnetic applications. They can be used as sensors, sensitive elements of magnetometers, magnetic filters, ferrofluids, xerography, magneto-resonance imaging, magnetic hypothermia, and biomedical applications. The superior application of oriented MFCNT arrays can be in a sphere of magnetic write/read heads and high-density data storage devices [33–36]. The FSL irradiation may become an instrument for the machining of the mentioned devices based on the arrays of MFCNTs. In particular, in the present work, we investigate the surface morphology
modification of the vertically aligned MFCNTs upon FSL irradiation and Selleck APR-246 properties of the products obtained after irradiation and develop the mechanism of the interaction of FSL with such complicated media as the arrays of MFCNTs. Methods CNT arrays were synthesized on Si substrates by the floating catalyst CVD via a high-temperature pyrolysis of the xylene/ferrocene solution injected into the reaction zone of quartz reactor. In our particular case, the concentration of ferrocene in the solution was 10%; the temperature in the reaction zone was 875°C, and the process duration was 30 s. Obtained as a result of ferrocene decomposition, Fe phase nanoparticles serve as catalyst for CNTs growth. During the growth process, these nanoparticles are intercalating into CNT arrays and are considered as fillers of CNTs. The morphology of the CNT arrays before and after the FSL irradiation was investigated by scanning electron microscopy (SEM) (Hitachi
S-4800 FE-SEM, Chiyoda-ku, Japan). For Raman measurements, Renishaw micro-Raman Spectrometer (Series1000, Renishaw, Wotton-under-Edge, UK) with ID-8 laser beam of 1.5 mW incident power and 514 nm wavelength was used. The structure of CNTs was characterized by transmission electron microscopy (TEM, JEM 100-CX, JEOL) and a high-resolution TEM (JEM-2010, JEOL Ltd., Akishima-shi, Japan). For X-ray diffraction analysis (XRD), DRON-3 diffractometer (Bourevestnik, Inc., GSK2126458 concentration Maloochtinskiy, Russia) was used; the local configurations of iron ions of CNTs fillers were examined with Mössbauer spectroscopy (spectrometer MS2000 with Fe/Rh source, 40 mCu). Elemental analysis was made by energy-dispersive X-ray spectroscopy (EDX) (SUPRA-55WDS with the EDX prefix, Carl Zeiss, Inc., Oberkochen, Germany).